

Library access won’t allow upload, this will.
My knowledge here isn’t super deep, but it seems like you can do mapping per-share-per-ip, which means you can say “all file access coming from the immich host to this share will act as this user” which I think is fine if that share belongs to that user, and you don’t have anything else coming from that host to that share which you want to act as a different user. Which are very big caveats.
Sorry I misread when you said “library” for some reason I thought you meant “external library”
The problem that I’m trying to solve and I think OP is also trying to solve, is that they want the files to be on their NAS because it is high capacity, redundant, and backed up, but many users have access to the NAS, so they cannot rely on immich alone to provide access permissions, they need access permissions on the files themselves.
I solved this by having a separate share for every user, and then mounting that user’s share on their library (storage label).
It sounds like OP wants a single share, so having correct file ownership is important to restrict file access to the correct users who are viewing the filesystem outside of immich.
Not sure what you mean by your last paragraph, how do you assign a share to individual files (assume you mean directories) outside of immich’s need for storage?